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Preheat the oven to 350 degrees F.
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Line two large baking sheets with parchment paper and set aside.
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Whisk together the flour, cocoa powder and baking powder in a medium bowl and set aside.
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Add butter and 8 oz of bittersweet chopped chocolate to a small, microwave-safe bowl and melt in 30 seconds increments, stirring occasionally until smooth. Set aside to slightly cool.
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In a large bowl, whisk together the eggs, vanilla, and granulated sugar until light and fluffy.
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Add the slightly cooled melted chocolate mixture to the egg mixture and stir to combine.
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Slowly add the flour mixture and stir until it is well combined. Chill for 30 minutes in the refrigerator.
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In another medium bowl, mix powdered sugar with peanut butter until fully combined, then roll it into 1 inch balls. Making about 24 balls, arrange them on a cookie tray covered with waxed paper. Set aside.
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Scoop about 1 1/2 - 2 tablespoons of dough onto the prepared baking sheets.
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Bake for 10 minutes or until the cookies look firm on the outside, careful to not overbake!
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Remove cookies from oven and immediately press lightly the peanut butter balls lightly into the center of each cookie. Cool the cookies for 5 minutes on the baking sheet, after that transfer to onto a cooling rack.
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Melt the semisweet chocolate in 30 seconds increments using the microwave, and stirring after each round. Spoon melted chocolate over the peanut butter balls.
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Chill for 10 minutes for the chocolate to settle and serve.